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SUBSTRATE REDUCTION KINETICS AND PERFORMANCE EVALUATION OF FLUIDIZED-BED REACTOR FOR TREATMENT OF BREWERY WASTEWATER
Abstract
pilot scale anaerobic fluidized-bed reactor was operated for treating brewery wastewater at nine different hydraulic retention time (HRTs) of 2, 3, 4, 5, 6, 7, 8, 9, and 10hr. The COD reduction efficiencies increased from 9.8% to 74.1% with increasing HRT from 2 to 10hr.Similarly, the corresponding BOD5 reduction efficiencies increased from 38.0% to 92.9% with the same increase in HRT. The predicted effluent substrate concentration values of Modified Stover–Kincannon model were found to be in strong agreement with the experimental values. This is due to proper solubilization and consumption of entrapped substrates in the fluidized-bed reactor since the microbial cells have maximum opportunity to interact with the entrapped substrates in the reactor. The kinetic parameters were determined using existing linear models with experimental data. Modified Stover-Kincannon model showed high correlation coefficient (R2= 0.9996) only in predicted effluent concentration of wastewater. This shows that this model can be best used to predict effluent COD concentration in a fluidized bed reactor treating brewery wastewater. Similarly, FIRST ORDER MODEL has the highest correlation coefficient in the plot using experimental data. This means that first order model can be used to represent the real biological degradation that takes place during the treatment of waste water by microorganisms in a fluidized-bed reactor system treating brewery wastewater. This model and kinetic parameters obtained in this work can be employed in the design of industrial size- fluidized bed reactor for treatment of brewery waste water. Maximum utilization rate constant (Umax) determined is 11.75g COD/l.hr and the saturation value constant (KB) 131.41g COD/l.hr was also determined. The values of kinetic constants were also used to predict the effluent COD concentration. It was observed that the simulated data (predicted data) were in good harmony with the experimental data counterpart in modified Stover –Kicannon model, The strength of the above-mentioned model can be observed from the correlation coefficient obtained from the model asR2 =0.9996 in modified Stover-kicannon model.