Isotopic profiling of natural uranium mined from northern Nigeria for nuclear forensic application.

Abstract

Four mined samples of natural uranium from northern Nigeria were studied through inductively coupled plasma mass spectrometry, at the Environmental Analytical Chemistry Laboratory, University of the Witwatersrand, Johannesburg. The samples were characterised for lead, thorium and uranium isotopic
concentrations, isotopic ratios and age. The objective was to obtain nuclear forensic fingerprints as baseline data to add to the Nigerian National Nuclear Forensic Library. Results showed significant variation in the isotopic concentrations of lead, thorium and uranium across the mines. Isotopic ratios of ²³⁸U/²³⁵U, ²³⁵U/²³⁸U and ²³⁴U/²³⁸U across the sample of 137.881±0.007, 7.253×10^-03±2.05×10^-04 and 5.540×10^-05±4.08×10^-07 were found to be consistent with the natural values. The age of natural uranium is comparable to the age of earth. Uranium, lead, and thorium isotopic concentrations and ratios, as well as the age of the samples characterised, provide an isotopic profile that can be used for nuclear forensic application.
Significance:
• Given the abundant deposits of natural uranium in Africa and the consequent potential for nuclear insecurity, determining the isotopic profiles and signatures of natural uranium is important for application in nuclear forensics.
• Isotopic concentrations of ²³²Th, ²³⁸U, ²³⁵U and ²³⁴U from the respective sampling sites differed significantly, thereby providing characteristic isotopic profiles.