Article Sidebar
Published:
Oct 13, 2015Keywords:
Article Details
Copyright for articles published in this journal is retained by the journal.
SAJChem applies the Creative Commons Attribution (CC BY) license to manuscripts we publish. This license was developed to facilitate open access – namely, free immediate access to, and unrestricted reuse of, original works of all types. Under this license, authors agree to make articles legally available for reuse, without permission or fees, for virtually any purpose. Anyone may copy, distribute or reuse these articles, as long as the author and original source are properly cited.
Main Article Content
Synthesis, Characterization and Application of Nano Lepidocrocite and Magnetite in the Degradation of Carbon Tetrachloride
Abstract
Degradation of halogenated organic compounds using nanoparticles is one of the innovative technologies in environmental remediation. In the present study, the synthesis, characterization and application of lepidocrocite (FeOOH) and magnetite (Fe3O4) nanoparticles for the remediation of water contaminated with carbon tetrachloride (CCl4) has been investigated. The synthesized nanoparticles were characterized by using advanced instrumental techniques such as field emission scanning electron microscopy (FESEM) and X-ray diffraction (XRD). The synthesized FeOOH and Fe3O4 nanoparticles were found to have an average crystallite size of 10.94 nm and 18.10 nm, respectively. Batch degradation experiments for the degradation of CCl4 were carried out separately using both of the above synthesized nanoparticles. The degradation reactions were found to be first-order while using Fe3O4 and second-order while using FeOOH nanoparticles. Moreover, the reactivity of freshly synthesized Fe3O4 nanoparticles was found to be much higher than that of FeOOH nanoparticles.
Keywords: Nanoparticles, magnetite, lepidocrocite, carbon tetrachloride, degradation kinetics
