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Published:
Jun 1, 1988Keywords:
ɣ-picoline adducts spectroscopic properties Metal ( II) furoylacetonates
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The copyright of a submitted article is only transferred to the publishers if and when the article is accepted for publication. All rights reserved. No part of this publication may be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, electrostatic, mechanical, photocopying, recording or otherwise without the prior written permission of the publishers.
Main Article Content
Syntheses and some Properties of Bis(furoylacetonato) Metal (11) and their ɣ -Picoline Adducts
Abstract
The hydrated anhydrous complexes alongside the ɣ -picoline adducts of bis (furoylacetonato ) metal( II I of the form M(fbc1)2.nH20 and M(fbd)2 ( e -picin, where n = 0,1 or 2, M = Mn ( I I ), Co( I I I , Ni( II ) Cu( II) and Zn( II ):Hfbd = furoylace-tone, have been prepared and charac-terised using microanalytical data, mag-netic moment, infrared and reflectance electronic spectra. All of the complexes have octahedral geometry with the exception of Zn (fbc1) . H2O and Cu (fbd12 ( ɣ -pic) which are square pyramidal. The anhydrous Cu (fbd) is square planar.
