Kinetic Evaluation of Naphthalene Removal using Acid - Modified and Unmodified Bentonite Clay Mineral

Abstract

Kinetic evaluation of naphthalene onto acid – modified and unmodified
bentonite clay mineral was investigated by means of the effects of  concentration, contact time and pH. The amount of naphthalene adsorbed was determined spectrophotometrically. The optimum pH value and  equilibrium contact time for the adsorption of naphthalene onto acid –
modified and unmodified samples were found to be 6.0 and 30 minutes, respectively. The maximum adsorption capacity (qm) for acid – modified and unmodified adsorbents was found to be 10.52 mg/g and 5.56 mg/g. These values were close with the experimental data (qe) obtained from the adsorption of naphthalene onto acid – modified (9.0 mg/g) and  unmodified (4.0 mg/g) adsorbents. The adsorption isotherm fitted well with Langmuir equation model for the acid – modified than the unmodified adsorbent. Kinetic evaluations of the adsorption showed that the process followed the pseudo – second – order equation model. The results obtained showed that modified bentonite clay mineral was reasonably effective adsorbent for the removal of naphthalene (organic contaminant), which is an important source for environmental pollutant. ©JASEM

KEYWORDS: Naphthalene, equilibrium, kinetics, sorption, acid – modified bentonite.