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Synthesis, infrared and mossbauer studies of two new oxalato SnPh2Cl2 and SnPh2Cl(OH) adducts


Y Sow
L Diop
JD Ardisson

Abstract

Two new oxalato chloridodiorganostannic adducts have been synthesized, their elemental analyses performed, infrared and Mossbauer studies carried out. Discrete cages or a double discrete cages structures have been  suggested, the oxalate behaving as a monocoordinating or a monochelating donor. The key role of R2NH2+ cations, involved in NH…O hydrogen bonds is noteworthy.

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Keywords: Diorganostannic residues, infrared, Mossbauer, cage, coordinating oxalate.


Journal Identifiers


eISSN: 1997-342X
print ISSN: 1991-8631