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Synthesis, infrared and mossbauer studies of two new oxalato SnPh2Cl2 and SnPh2Cl(OH) adducts
Abstract
Two new oxalato chloridodiorganostannic adducts have been synthesized, their elemental analyses performed, infrared and Mossbauer studies carried out. Discrete cages or a double discrete cages structures have been suggested, the oxalate behaving as a monocoordinating or a monochelating donor. The key role of R2NH2+ cations, involved in NH…O hydrogen bonds is noteworthy.
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Keywords: Diorganostannic residues, infrared, Mossbauer, cage, coordinating oxalate.