JOE Otaigbe
Department of Pure and Industrial Chemistry, University of PortHarcourt, P. M. B. 5323, Port Harcourt, Rivers State, Nigeria.
CC Onyemenonu Snr
Department of Pure and Industrial Chemistry, University of PortHarcourt, P. M. B. 5323, Port Harcourt, Rivers State, Nigeria.
Abstract
The effects of Adopol EVS-9279X on the emulsion and film properties of poly (vinyl acetate) and acrylic resin were investigated using 5% - 10% w/w sample formulations. Results indicate that Adopol EVS-9279X increased the surface tension of poly (vinyl acetate) from 2.060 x 10-3Nm-1 to a maximum of 8.966 x 10-2 Nm-1 at 9% w/w formulation and reduced same for acrylic resin from 3.988 x 10-2Nm-1 to 2.702 x 10-2Nm-1 at 6% - 7% w/w formulations. It lowered the solid content of poly (vinyl acetate) and acrylic resin from 38.2% to 33.3% and 45.8% to 41.8% respectively at 10% w/w formulation. Water resistance was improved by a reduction in water absorption from 45.8% to 38.5% minimum for poly (vinyl acetate) and 37.2% to 34.0% minimum for acrylic resin at 5% w/w formulation.
Drying time was reduced from 74 minutes to 51 minutes at 5% w/w formulation for poly (vinyl acetate) and 68 minutes to 58 minutes at 7% w/w formulation for acrylic resin. Specific gravity was lowered from 1.05 to 0.91 at 6% w/w formulation for acrylic resin, while pH was lowered at low concentration from 4.70 to 4.49 at 6% w/w formulation for poly (vinyl acetate) and 8.86 to 8.50 at 9% w/w formulation for acrylic resin. Apparent viscosities and flexibility were unaltered within the concentration range of 5% - 10% w/w formulation studied for both polymers.
Key Words: Emulsion, Adopol EVS-9279X, Polymer.
Global Jnl Pure & Applied Sciences Vol.10(2) 2004: 307-314