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Synthesis, magnetic and spectroscopic studies of Ni(II), Cu(II), Zn(II) and Cd(II) complexes of a newly Schiff base derived from 5-bromo-2-hydroxybezylidene)-3,4,5-trihydroxybenzohydrazide)


Abeer A. Alhadi
Shayma A. Shaker
Wagee A. Yehye
Hapipah Mohd Ali
Mahmood A. Abdullah

Abstract

A new hydrazide Shiff base ligand GHL1 (5-bromo-2-hydroxybezylidene)-3,4,5-trihydroxybenzohydrazide) was prepared by refluxing of trihydroxybenzhydrazide with an ethanolic of 5-bromo-2-hydroxybenzaldehyde. The ligand reacted with Ni(II), Cu(II), Zn(II) and Cd(II) (acetate salts). All the complexes were characterized by elemental analysis, molar conductivity, TGA, UV-Vis and FT-IR spectral studies. All the complexes have octahedral geometry except Ni(II) complex which has tetrahedral geometry.

 

KEY WORDS: Hydrazone complexes, Schiff base ligand, Spectral studies

 

Bull. Chem. Soc. Ethiop. 2012, 26(1), 95-101.

DOI: http://dx.doi.org/10.4314/bcse.v26i1.10


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eISSN: 1726-801X
print ISSN: 1011-3924