Thermodynamics of ion exchange equilibrium for some uni-univalent and divalent reaction systems using strongly basic anion exchange resin Indion FF-IP

Abstract

The study on thermodynamics of ion exchange equilibrium for uni-univalent Cl^-/I^-, Cl^-/Br^-, and uni-divalent Cl^-/SO₄^2-, Cl^-/C₂O₄^2- reaction systems was carried out using ion exchange resin Indion FF-IP. The equilibrium constant K was calculated by taking into account the activity coefficient of ions both in solution as well as in the resin phase. For uni-univalent ion exchange reaction systems, the equilibrium constant K’ were also calculated by considering mole fraction of ions in the resin phase. The K values calculated for uni-univalent and uni-divalent anion exchange reaction systems were observed to increase with rise in temperature, indicating the endothermic exchange reactions having enthalpy values of 22.45, 28.57, 17.84, 15.97 kJ/mol, respectively.

KEY WORDS: Ion exchange equilibrium, Equilibrium constant in standard state, Apparent equilibrium constant, Enthalpy, Endothermic reaction

Bull. Chem. Soc. Ethiop. 2008, 22(3), 415-421.