Al2O3/Fe3O4/ZrO2 ternary oxide sorbent: Synthesis, characterization and sorption behavior to fluoride and phosphate ions from aqueous solution

Abstract

ABSTRACT. Excess quantities of fluoride and phosphate in water bodies can lead to fluorosis and eutrophication problems, respectively. In search of a promising adsorbent targeting these ions, Fe₃O₄/Al₂O₃/ZrO₂ ternary oxide was synthesized via co-precipitation method and characterized by X-ray diffraction (XRD), Fourier transform-infrared (FTIR) and Brunauer-Emmer-Teller (BET). Its specific surface area was found to be 205 m²/g. The effects of solution pH, adsorbent dose, contact time, agitation speed and initial fluoride and phosphate concentrations were also investigated and the optimum values were 4, 0.5 g, 12 h, 100 rpm and 20 mg/L, respectively, for fluoride and 5, 0.1 g, 8 h, 100 rpm and 10 mg/L, respectively, for phosphate. Fluoride and phosphate adsorptions fitted well with Freundlich and Langmuir isotherm models, respectively and their kinetic data correlated well with the pseudo-second order model. Desorbability study revealed that maximum desorption was achieved at pH 12. Thermodynamics study on the other hand showed that adsorption of fluoride was nonspontaneous and endothermic whereas that of phosphate was spontaneous and exothermic. Application on real water sample decreased the concentration of fluoride from 4.92 to 1.97 mg/L in ground water and phosphate from 1.7 to 0.35 mg/L lake water showing its potential as a promising adsorbent.

KEY WORDS: Adsorption, Fluoride, Phosphate, Ternary oxide sorbent, Isotherm models

Bull. Chem. Soc. Ethiop. 2022, 36(3), 555-569.                                                              

DOI: https://dx.doi.org/10.4314/bcse.v36i3.6