Heck-Matsuda reaction utilizing in-situ generated palladium on aluminum phosphate

Abstract

ABSTRACT. Pd on AlPO₄-catalyst was prepared by a one-pot process using Pd(OAc)₂ and AlPO₄ in methanol as solvent. The synthesized catalyst was used in the monoarylation of olefins via the Heck-Matsuda reaction. Several functionalized arylvinylphosphonates, cinnamic derivatives and benzalacetones could be obtained in good to excellent yields.

KEY WORDS: Arylvinylphosphonates, Benzalacetones, Cinnamic derivatives, Palladium on Aluminum phosphate, Kinetic studies

Bull. Chem. Soc. Ethiop. 2022, 36(2), 423-432.                                                               

DOI: https://dx.doi.org/10.4314/bcse.v36i2.15