Four new tin(II), uranyl(II), vanadyl(II), and zirconyl(II) alloxan biomolecule complexes: synthesis, spectroscopic and thermal characterizations

Abstract

ABSTRACT. The alloxan as a biomolecule ligand has been utilized to synthesize thermodynamically and kinetically stabilized four new tin(II), uranyl(II), vanadyl(II), and zirconyl(II) complexes. In the complexes, tin(II) ion present is in tetrahedral arrangement, zirconyl and vanadyl(II) ions present are in square pyramid feature but uranyl(II) ion present is in octahedral arrangement and all are coordinated by two bidentate alloxan ligand in complexes. The synthesized alloxan ligand coordinate with central metal(II) ion through oxygen in position C₂=O and the nitrogen in position N₁ developing a 4-membered chelate ring. Synthesized Sn(II), UO₂(II), VO(II), and ZrO(II) complexes via bidentate ligand have been accurately described by various spectroscopic techniques like elemental analysis (C, H, N, metal), conductivity measurements, FT-IR, UV-Vis, ¹H-NMR, and TGA. The kinetic thermodynamic parameters such as: E*, ΔH*, ΔS* and ΔG* were calculated using Coats and Redfern and Horowitz and Metzger equations.

KEY WORDS: Alloxan, Metal ions, Spectroscopy, Ligand, Coordination, Thermogravimetry

Bull. Chem. Soc. Ethiop. 2022, 36(2), 373-385.   

DOI: https://dx.doi.org/10.4314/bcse.v36i2.11