SYNTHESIS OF ALLENIC NAPHTHALENE DERIVATIVES

Abstract

Propargylic alcohol of naphthalene derivatives were synthesized and converted to the corresponding propargylic acetate using acetic anhydride. Reduction of the propargylic acetates by SmI₂ afforded allenes and acetylenes. Base-promoted isomerisation of acetylene formed allene in high yield.

KEY WORDS: Isomerisation, Allenic derivatives of naphthalene


Bull. Chem. Soc. Ethiop. 2007, 21(2), 241-247.