Solid-state synthesis and physico-chemical characterization of modified smectites using natural clays from Burkina Faso

Abstract

Solid-state intercalation was applied to prepare organo-smectites using cationic surfactants and natural clays containing smectite at various surfactant/smectite ratios. The surfactants enter the interlayers of smectites causing a swelling of the clays. The used clays were collected in Siétougou and Diabari villages located in the eastern part of Burkina Faso. The solid-state intercalation was successful for all four surfactants applied, n-dodecyltrimethylammonium bromide, (n-C₁₂H₂₅(CH₃)₃NBr), n-tetradecyltrimethylammonium bromide, (n-C₁₄H₂₉(CH₃)₃NBr), n-hexadecyltrimethylammonium bromide (n-C₁₆H₃₃(CH₃)₃NBr) and di-n-dodecyldimethyl­ammonium bromide ((n-C₁₂H₂₅)₂(CH₃)₂NBr) at different levels of the cation exchange capacity (CEC). The synthesized organo-smectites were characterized regarding relative density, structural and textural properties. XRPD data showed a systematic increase of the basal spacing of the unit cell of the smectite up to >38 Å at 2.0-CEC loading of the surfactant. This increase indicates that the surfactants penetrated into the smectite interlayers with the surfactants being arranged parallel to the layers at low concentrations and almost perpendicular at high ones. FTIR spectra of the organo-smectites showed a decrease in the intensities of the water bands at around 1630 cm^-1 and 3400 cm^-1, and new specific bands close to 2920 cm^-1 and 2850 cm^-1 were assigned to the asymmetric and symmetric stretching of CH₂ groups of the surfactants, respectively.

KEY WORDS: Smectite, Organo-smectite, Surfactant, Intercalation

Bull. Chem. Soc. Ethiop. 2021, 35(1), 43-59.

DOI: https://dx.doi.org/10.4314/bcse.v35i1.4