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The use of methemoglobin complex in estimating cyanogen potential of cassava and cassava products


JC Ajaelu
JT Bamgbose
BO Atolaiye
AA Adetoye

Abstract

An improved method of analysis of cyanide in cassava and cassava products using methemoglobin complex is described. The cyanogen content of cassava mash, pre-fufu mash, fufu and Gari was
determined spectrophotometrically. Optimal conditions were determined to be 24 h at 370C in phosphate buffer (0.05 M; pH 5.6). The average cyanogen content obtained were 14.68 ± 0.66, 13.49 ± 0.02, 11.94 ±
0.02 and 9.87 ± 0.64 mg/kg for cassava mash, pre-fufu, fufu and gari, respectively. The values estimated for cassava mash and pre-fufu are greater than the values obtained for the processed fufu and gari, and
also greater than the WHO safe value for cassava flour (10 mg/kg). The fact that the results of this work gave lower values of cyanide in processed cassava products compared with the value of unprocessed cassava suggests the validity of this method.

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eISSN: 1684-5315